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OZONE IN THE ATMOSPHERE

What is ozone and where is it in the atmosphere?
Ozone is a gas that is naturally present in our atmosphere. Each ozone molecule contains three atoms of oxygen and is denoted chemically as O3. Ozone is found primarily in two regions of the atmosphere. About 10% of atmospheric ozone is in the troposphere, the region closest to Earth (from the surface to about 10-16 kilometers (6-10 miles)). The remaining ozone (90%) resides in the stratosphere, primarily between the top of the troposphere and about 50 kilometers (31 miles) altitude. The large amount of ozone in the stratosphere is often referred to as the “ozone layer.”

How is ozone formed in the atmosphere?
Ozone is formed throughout the atmosphere in multistep chemical processes that require sunlight. In the stratosphere, the process begins with the breaking apart of an oxygen molecule (O2 ) by ultraviolet radiation from the Sun. In the lower atmosphere (troposphere), ozone is formed in a different set of chemical reactions involving hydrocarbons and nitrogen-containing gases.

Is there an ozone hole over the Arctic?
Significant reductions in ozone content in the stratosphere above the Arctic have been observed during the late winter and early spring (January-March) in 6 of the last 9 years. However, these reductions, typically 20-25%, are much smaller than those observed currently each spring over the Antarctic (the ozone hole).

The difference between ozone content in the two polar regions (see figure below) is caused by the dissimilar weather patterns. The Antarctic continent is a very large land mass surrounded by oceans. This symmetrical condition produces very low stratospheric temperatures within a meteorologically isolated region, the so-called polar vortex, which extends from about 65°S to the pole. The cold temperatures lead in turn to the formation of clouds, known as polar stratospheric clouds. These clouds provide chemical changes that promote production of chemically active chlorine and bromine that rapidly destroy ozone. The conditions that maintain elevated levels of chemically active chlorine and bromine persist into September and October in Antarctica, when sunlight returns over the region to initiate ozone depletion.

The winter meteorological conditions in the Northern Hemisphere, just like in the Southern Hemisphere, lead to the formation of an isolated region bounded by strong winds, in which the temperature is also cold enough for polar stratospheric clouds to form. However, the geographic symmetry about the North Pole is less than about the South Pole. As a result, large-scale weather systems disturb the wind flow, making it less stable over the Arctic region than over the Antarctic continent. These disturbances prevent the temperature in the Arctic stratosphere from being as cold as in the Antarctic stratosphere, and fewer polar stratospheric clouds are therefore formed. Nevertheless, chemically active chlorine and bromine compounds are also formed over the Arctic, as they are over Antarctica, from reactions at the surface of the clouds. But the cold conditions rarely persist into March, when sufficient sunlight is available to initiate large ozone depletion.

In recent years, there has been a string of unusually cold winters in the Arctic, compared with those in the preceding 30 years. The cold and persistent conditions have led to enhanced ozone depletion, since the atmospheric concentrations of ozone-depleting gases have also been relatively large during these years. However, the cause of the observed change in meteorological conditions is not yet understood. Such conditions might persist over the coming years, further enhancing ozone depletion. But it is also possible that, in the next few years, they could revert to conditions characteristic of a decade ago. In the latter case, chemical ozone depletion in the Arctic would be expected to diminish.

Therefore, although there has been significant ozone depletion in the Arctic in recent years, it is difficult to predict what may lie ahead, because the future climate of the Arctic stratosphere cannot be predicted with confidence.

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When did the Antarctic ozone hole first appear?
The Springtime Antarctic ozone hole is a new phenomenon that appeared in the early 1980s.

The observed average amount of ozone during September, October, and November over the British Antarctic Survey station at Halley, Antarctica, first revealed notable decreases in the early 1980s, compared with the preceding data obtained starting in 1957. The ozone hole is formed each year when there is a sharp decline (currently up to 60%) in the total ozone over most of Antarctica for a period of about three months (September-November) during spring in the Southern Hemisphere. Late-summer (January-March) ozone amounts show no such sharp decline in the 1980s and 1990s. Observations from three other stations in Antarctica and from satellite-based instruments reveal similar decreases in springtime amount of ozone overhead. Balloon-borne ozone instruments show dramatic changes in the way ozone is distributed with altitude. As the figure below from the Syowa site shows, almost all of the ozone is now depleted at some altitudes as the ozone hole forms each springtime, compared to the normal ozone profile that existed before 1980. As explained in an earlier question (page *), the ozone hole has been shown to result from destruction of stratospheric ozone by gases containing chlorine and bromine, whose sources are mainly human-produced halocarbon gases.

Before the stratosphere was affected by human-produced chlorine and bromine, the naturally occurring springtime ozone levels over Antarctica were about 30-40% lower than springtime ozone levels over the Arctic. This natural difference between Antarctic and Arctic conditions was first observed in the late 1950s by Dobson. It stems from the exceptionally cold temperatures and different winter wind patterns within the Antarctic stratosphere as compared with the Arctic. This is not at all the same phenomenon as the marked downward trend in total ozone in recent years.

Changes in stratospheric meteorology cannot explain the ozone hole. Measurements show that wintertime Antarctic stratospheric temperatures of past decades had not changed prior to the development of the ozone hole each September. Ground, aircraft, and satellite measurements have provided, in contrast, clear evidence of the importance of the chemistry of chlorine and bromine originating from human-made, compounds in depleting Antarctic ozone in recent years.

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Why has an ozone hole appeared over Antarctica when CFCs and Halons are released mainly in the Northern Hemisphere?
The Earth's atmosphere is continuously stirred over the globe by winds. As a result, ozone-depleting gases get mixed throughout the atmosphere, including Antarctica, regardless of where they are emitted. The special meteorological conditions in Antarctica cause these gases to be more effective there in depleting ozone compared to anywhere else.

Human emissions of chlorofluorocarbons (CFCs) and halons (bromine-containing gases) have occurred mainly in the Northern Hemisphere. About 90% have been released in the latitudes corresponding to Europe, Russia, Japan, and North America. Gases such as CFCs and halons, which are insoluble in water and relatively unreactive, are mixed within a year or two throughout the lower atmosphere. The CFCs and halons in this well-mixed air rise from the lower atmosphere into the stratosphere mainly in tropical latitudes. Winds then move this air poleward - both north and south - from the tropics, so that air throughout the global stratosphere contains nearly equal amounts of chlorine and bromine.

In the Southern Hemisphere, the South Pole is part of a very large land mass (Antarctica) that is completely surrounded by ocean. This symmetry is reflected in the meteorological conditions that allow the formation in winter of a very cold region in the stratosphere over the Antarctic continent, isolated by a band of strong winds circulating around the edge of that region. The very low stratospheric temperatures lead to the formation of clouds (polar stratospheric clouds) that are responsible for chemical changes that promote production of chemically active chlorine and bromine. This chlorine and bromine activation then leads to rapid ozone loss when sunlight returns to Antarctica in September and October of each year, which then results in the Antarctic ozone hole. As the figure below depicts, the magnitude of the ozone loss has generally grown through the 1980s as the amount of human-produced ozone-depleting compounds has grown in the atmosphere.

Similar conditions do not exist over the Arctic. The wintertime temperatures in the Arctic stratosphere are not persistently low for as many weeks as over Antarctica, which results in correspondingly less ozone depletion in the Arctic (see the next question).

Does most of the Chlorine in the stratosphere come from human or natural sources?
Most of the chlorine in the stratosphere is there as a result of human activities, as the figure below illustrates.

Many compounds containing chlorine are released at the ground. Those that dissolve in water cannot reach stratospheric altitudes in significant amounts because they are "washed out" of the atmosphere in rain or snow. For example, large quantities of chlorine are released from evaporated ocean spray as sea salt (sodium chloride) particles. However, because sea salt dissolves in water, this chlorine is taken up quickly in clouds or in ice, snow, or rain droplets and does not reach the stratosphere. Another ground-level source of chlorine is from its use in swimming pools and as household bleach. When released, this chlorine is rapidly converted to forms that dissolve in water and therefore are removed from the lower atmosphere. Such chlorine never reaches the stratosphere in significant amounts. Volcanoes can emit large quantities of hydrogen chloride, but this gas is rapidly converted to hydrochloric acid, which dissolves in rain water, ice, and snow and does not reach the stratosphere. Even in explosive volcanic plumes that rise high in the atmosphere, nearly all of the hydrogen chloride is removed by precipitation before reaching stratospheric altitudes. Finally, although the exhaust from the Space Shuttle and from some rockets does inject some chlorine directly into the stratosphere, the quantities are very small (less than 1% of the annual input from halocarbons in the present stratosphere).

In contrast, the major ozone-depleting human-produced halocarbons - such as chlorofluorocarbons (CFCs) and carbon tetrachloride (CCl4) - are not soluble in water, do not react with snow or other natural surfaces, and are not broken down chemically in the lower atmosphere. Therefore, these and other human-produced substances containing chlorine do reach the stratosphere.

Several pieces of evidence combine to establish human-produced halocarbons as the primary source of stratospheric chlorine. First, measurements have shown that the chlorinated species that rise to the stratosphere are primarily manufactured compounds [mainly CFCs, carbon tetrachloride, methyl chloroform, and the hydrochlorofluorocarbon (HCFC) substitutes for CFCs], together with small amounts of hydrochloric acid (HCl) and methyl chloride (CH3Cl), which are partly natural in origin. Second, researchers have measured nearly all known gases containing chlorine in the stratosphere. They have found that the emissions of the human-produced halocarbons, plus the much smaller contribution from natural sources, could account for all of the stratospheric chlorine. Third, the increase in total stratospheric chlorine measured between 1980 and 1998 corresponds to the known increases in concentrations of human-produced halocarbons during that time.

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Why do we care about atmospheric ozone?
Ozone in the stratosphere absorbs some of the Sun’s biologically harmful ultraviolet radiation. Because of this beneficial role, stratospheric ozone is considered “good ozone.” In contrast, ozone at Earth’s surface that is formed from pollutants is considered “bad ozone” because it can be harmful to humans and plant and animal life. Some ozone occurs naturally in the lower atmosphere where it is beneficial because ozone helps remove pollutants from the atmosphere.

Is total ozone uniform over the globe?

No, the total amount of ozone above the surface of Earth varies with location on time scales that range from daily to seasonal. The variations are caused by stratospheric winds and the chemical production and destruction of ozone. Total ozone I s generally lowest at the equator and highest near the poles because of the seasonal wind patterns in the stratosphere.

How is ozone measured in the atmosphere?
The amount of ozone in the atmosphere is measured by instruments on the ground and carried aloft in balloons, aircraft, and satellites. Some measurements involve drawing air into an instrument that contains a system for detecting ozone. Other measurements are based on ozone’s unique absorption of light in the atmosphere. In that case, sunlight or laser light is carefully measured after passing through a portion of the atmosphere containing ozone.

Can natural changes such as the sun's output and volcanic eruptions be responsible for the observed changes in ozone?
Although there are natural forces that cause fluctuations in ozone amounts, there is no evidence that natural changes are contributing significantly to the observed long-term trend of decreasing ozone.

The formation of stratospheric ozone is initiated by ultraviolet (UV) light coming from the Sun. As a result, the Sun's output affects the rate at which ozone is produced. The Sun's energy release (both as UV light and as charged particles such as electrons and protons) does vary, especially over the well-known 11-year sunspot cycle. Observations over several solar cycles (since the 1960s) show that total global ozone levels vary by 1-2% from the maximum to the minimum of a typical cycle. However, changes in the Sun's output cannot be responsible for the observed long term changes in ozone, because the ozone downward trends are much larger than 1-2%. As the figure below shows, since 1978 the Sun's energy output has gone through maximum values in about 1980 and 1991 and minimum values in about 1985 and 1996. It is now increasing again toward its next maximum around the year 2002. However, the trend in ozone was downward throughout that time. The ozone trends presented in this and previous international scientific assessments have been obtained by evaluating the long-term changes in ozone after accounting for the solar influence (as has been done in the figure below).

Major, explosive volcanic eruptions can inject material directly into the ozone layer. Observations and model calculations show that volcanic particles cannot on their own deplete ozone. It is only the interaction of human-produced chlorine with particle surfaces that enhances ozone depletion in today's atmosphere. Specifically, laboratory measurements and observations in the atmosphere have shown that chemical reactions on and within the surface of volcanic particles injected into the lower stratosphere lead to enhanced ozone destruction by increasing the concentration of chemically active forms of chlorine that arise from the human-produced compounds like the chlorofluorocarbons (CFCs). The eruptions of Mt. Agung (1963), Mt. Fuego (1974), El Chichón (1982) and particularly Mt. Pinatubo (1991) are examples. The eruption of Mt. Pinatubo resulted in a 30- to 40-fold increase in the total surface area of particles available for enhancing chemical reactions. The effect of such natural events on the ozone layer is then dependent on the concentration of chlorine-containing molecules and particles available in the stratosphere, in a manner similar to polar stratospheric clouds. Because the particles are removed from the stratosphere in 2 to 5 years, the effect on ozone is only temporary, and such episodes cannot account for observed long-term changes. Observations and calculations indicate that the record-low ozone levels observed in 1992-1993 reflect the importance of the relatively large number of particles produced by the Mt. Pinatubo eruption, coupled with the relatively higher amount of human-produced stratospheric chlorine in the 1990s compared to that at times of earlier volcanic eruptions.

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How can Chlorofluorocarbons (CFCs) get to the stratosphere if they're heavier than air? CFCs reach the stratosphere because the Earth's atmosphere is always in motion and mixes the chemicals added into it.

CFC molecules are indeed several times heavier than air. Nevertheless, thousands of measurements from balloons, aircraft, and satellites demonstrate that the CFCs are actually present in the stratosphere. This is because winds and other air motions mix the atmosphere to altitudes far above the top of the stratosphere much faster than molecules can settle according to their weight. Gases such as CFCs that do not dissolve in water and that are relatively unreactive in the lower atmosphere are mixed relatively quickly and therefore reach the stratosphere regardless of their weight.
Measured changes in concentration of constituents versus altitude teaches us more about the fate of compounds in the atmosphere. For example, the two gases carbon tetrafluoride (CF4, produced mainly as a by-product of the manufacture of aluminum) and CFC-11 (CCl3F, used in a variety of human activities) are both heavier than air.

Carbon tetrafluoride is completely unreactive at altitudes up to at least 50 kilometers in the atmosphere. Measurements show it to be nearly uniformly distributed throughout the atmosphere, as illustrated in the figure below. There have been measurements over the past two decades of several other completely unreactive gases, both lighter than air (neon) and heavier than air (argon and krypton), that show that they also mix upward through the stratosphere regardless of their weight.

CFC-11 is unreactive in the lower atmosphere and is similarly uniformly mixed there, as shown in the figure. However, the abundance of CFC-11 decreases as the gas reaches higher altitudes, because it is broken down by high-energy solar ultraviolet radiation. Chlorine released from this breakdown of CFC-11 and other CFCs remains in the stratosphere for several years, where every chlorine atom destroys many thousands of molecules of ozone.

What is the evidence that stratospheric ozone is destroyed by Chlorine and Bromine? Numerous laboratory investigations and analyses of worldwide measurements made in the stratosphere have demonstrated that chlorine- and bromine-containing chemicals destroy ozone molecules.

Research studies in the laboratory show that chlorine (Cl) reacts very rapidly with ozone. They also show that the reactive chemical chlorine monoxide (ClO) formed in that reaction can undergo further processes that regenerate the original chlorine, allowing the sequence to be repeated very many times (a chain reaction). Similar reactions also take place between bromine and ozone.

But do these ozone-destroying reactions occur in the "real world"? All the accumulated scientific experience demonstrates that the same chemical reactions do take place in nature. Many other reactions (including those of other chemical species) are often also taking place simultaneously in the stratosphere. This makes the connections among the changes difficult to untangle. Nevertheless, whenever chlorine (or bromine) and ozone are found together in the stratosphere, the ozone-destroying reactions are taking place.

Sometimes a small number of chemical reactions are so dominant in the natural circumstance that the connections are almost as clear as in laboratory experiments. Such a situation occurs in the Antarctic stratosphere during the springtime formation of the ozone hole. Independent measurements made by instruments from the ground and from balloons, aircraft, and satellites have provided a detailed understanding of the chemical reactions in the Antarctic stratosphere.

Large areas reach temperatures so low (less than -80°C, or -112°F) that stratospheric clouds form, which is a rare occurrence, except during the polar winters. These polar stratospheric clouds allow chemical reactions that transform chlorine species from those that do not cause ozone depletion into those that do. Among the latter is chlorine monoxide, which initiates ozone destruction in the presence of sunlight. The amount of reactive chlorine in such regions is therefore much higher than that observed in the middle latitudes, which leads to much faster chemical ozone destruction. The chemical reactions occurring in the presence of these clouds are now well understood from studies under laboratory conditions that mimic those found naturally in the atmosphere.

Scientists have repeatedly observed a large number of chemical species over Antarctica since 1986. Among the chemicals measured were ozone and chlorine monoxide, which is the reactive chemical identified in the laboratory as one of the participants in the ozone-destroying chain reactions. The satellite maps shown in the figure below relate the accumulation of chlorine monoxide observed over Antarctica and the subsequent ozone depletion that occurs rapidly in a few days over very similar areas.

Similar reactions involving chlorine and bromine have also been shown to occur during winter and spring in the Arctic polar regions, which leads to some chemical depletion of ozone in that region. Because the Arctic is not usually as persistently cold as the Antarctic, fewer stratospheric clouds form, and therefore there is less ozone depletion in the Arctic, which is the subject of a later question.

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THE OZONE DEPLETION PROCESS

What are the principal steps in stratospheric ozone depletion caused by human activities?
What emissions from human activities lead to ozone depletion?
What are the reactive halogen gases that destroy stratospheric ozone?
What are the chlorine and bromine reactions that destroy stratospheric ozone?
Why has an “ozone hole” appeared over Antarctica when ozone-depleting gases are present throughout the stratosphere?

What are the principal steps in stratospheric ozone depletion caused by human activities?
The initial step in the depletion of stratospheric ozone by human activities is the emission of ozone-depleting gases containing chlorine and bromine at Earth’s surface. Most of these gases accumulate in the lower atmosphere because they are unreactive and do not dissolve readily in rain or snow. Eventually, the emitted gases are transported to the stratosphere where they are converted to more reactive gases containing chlorine and bromine. These more reactive gases then participate in reactions that destroy ozone. Finally, when air returns to the lower atmosphere, these reactive chlorine and bromine gases are removed from Earth’s atmosphere by rain and snow.

What emissions from human activities lead to ozone depletion?
Certain industrial processes and consumer products result in the atmospheric emission of “halogen source gases.” These gases contain chlorine and bromine atoms, which are known to be harmful to the ozone layer. For example, the chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs), once used in almost all refrigeration and air conditioning systems, eventually reach the stratosphere where they are broken apart to release ozone-depleting chlorine atoms. Other examples of human-produced ozone-depleting gases are the “halons,” which are used in fire extinguishers and which contain ozone-depleting bromine atoms. The production and consumption of all principal halogen source gases by human activities are regulated worldwide under the Montreal Protocol.

What are the reactive halogen gases that destroy stratospheric ozone?
Emissions from human activities and natural processes are large sources of chlorine- and bromine-containing gases for the stratosphere. When exposed to ultraviolet radiation from the Sun, these halogen source gases are converted to more reactive gases also containing chlorine and bromine. Important examples of the reactive gases that destroy stratospheric ozone are chlorine monoxide (ClO) and bromine monoxide (BrO). These and other reactive gases participate in “catalytic” reaction cycles that efficiently destroy ozone. Volcanoes can emit some chlorine-containing gases, but these gases are ones that readily dissolve in rainwater and ice and are usually “washed out” of the atmosphere before they can reach the stratosphere.

What are the chlorine and bromine reactions that destroy stratospheric ozone?
Reactive gases containing chlorine and bromine destroy stratospheric ozone in “catalytic” cycles made up of two or more separate reactions. As a result, a single chlorine or bromine atom can destroy many hundreds of ozone molecules before it reacts with another gas, breaking the cycle. In this way, a small amount of reactive chlorine or bromine has a large impact on the ozone layer. Special ozone destruction reactions occur in polar regions because the reactive gas chlorine monoxide reaches very high levels there in the winter/spring season.

Why has an “ozone hole” appeared over Antarctica when ozone-depleting gases are present throughout the stratosphere?
Ozone-depleting gases are present throughout the stratospheric ozone layer because they are transported great distances by atmospheric air motions. The severe depletion of the Antarctic ozone layer known as the “ozone hole” forms because of the special weather conditions that exist there and nowhere else on the globe. The very cold temperatures of the Antarctic stratosphere create ice clouds called polar stratospheric clouds (PSCs). Special reactions that occur on PSCs and the relative isolation of polar stratospheric air allow chlorine and bromine reactions to produce the ozone hole in Antarctic springtime.

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STRATOSPHERIC OZONE DEPLETION

How severe is the depletion of the Antarctic ozone layer?
Is there depletion of the Arctic ozone layer?
How large is the depletion of the global ozone layer?
Do changes in the sun and volcanic eruptions affect the ozone layer?

How severe is the depletion of the Antarctic ozone layer?
Severe depletion of the Antarctic ozone layer was first observed in the early 1980s. Antarctic ozone depletion is seasonal, occurring primarily in late winter and spring (August-November). Peak depletion occurs in October when ozone is often completely destroyed over a range of altitudes, reducing overhead total ozone by as much as two-thirds at some locations. This severe depletion creates the “ozone hole” in ../images of Antarctic total ozone made from space. In most years the maximum area of the ozone hole usually exceeds the size of the Antarctic continent.

Is there depletion of the Arctic ozone layer?
Yes, significant depletion of the Arctic ozone layer now occurs in some years in the late winter/spring period (January-April). However, the maximum depletion is generally less severe than that observed in the Antarctic and is more variable from year to year. A large and recurrent “ozone hole,” as found in the Antarctic stratosphere, does not occur in the Arctic.

How large is the depletion of the global ozone layer?
The ozone layer has been depleted gradually since 1980 and now is about an average of 3% lower over the globe. The depletion, which exceeds the natural variations of the ozone layer, is very small near the equator and increases with latitude toward the poles. The large average depletion in polar regions is primarily a result of the late winter/spring ozone destruction that occurs there annually.

Do changes in the sun and volcanic eruptions affect the ozone layer?
Yes, factors such as changes in solar radiation, as well as the formation of stratospheric particles after volcanic eruptions, do influence the ozone layer. However, neither factor can explain the average decreases observed in global total ozone over the last two decades. If large volcanic eruptions occur in the coming decades, ozone depletion will increase for several years after the eruption.

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CONTROLLING OZONE-DEPLETING GASES

Are there regulations on production of ozone-depleting gases?
Has the Montreal Protocol been successful in reducing ozone-depleting gases in the atmosphere?

Are there regulations on production of ozone-depleting gases?
Yes, the production of ozone-depleting gases is regulated under a 1987 international agreement known as the “Montreal Protocol on Substances that Deplete the Ozone Layer” and its subsequent Amendment and Adjustments. The Protocol, now ratified by over 180 nations, establishes legally binding controls on the national production and consumption of ozone-depleting gases. Production and consumption of all principal halogen-containing gases by developed and developing nations will be significantly reduced or phased out before the middle of the 21st century.

Has the Montreal Protocol been successful in reducing ozone-depleting gases in the atmosphere?
Yes, as a result of the Montreal Protocol, the total abundance of ozone-depleting gases in the atmosphere has begun to decrease in recent years. If the nations of the world continue to follow the provisions of the Montreal Protocol, the decrease will continue throughout the 21st century. Some individual gases such as halons and hydrochlorofluorocarbons (HCFCs) are still increasing in the atmosphere, but will begin to decrease in the next decades if compliance with the Protocol continues. By mid-century, the effective abundance of ozone-depleting gases should fall to values present before the Antarctic “ozone hole” began to form in the early 1980s.

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IMPLICATIONS OF OZONE DEPLETION

Does ozone depletion cause climate change?
How severe is the ozone depletion now?
Is the ozone layer expected to recover?
Does depletion of the ozone layer increase ground-level ultraviolet radiation?
Is depletion of the ozone layer the principal cause of climate change?
Is the depletion of the ozone layer leading to an increase in ground-level Ultraviolet radiation?

Does ozone depletion cause climate change?
Ozone depletion and climate change are linked in a number of ways, but ozone depletion is not a major cause of climate change.

Atmospheric ozone has two effects on the temperature balance of the Earth. It absorbs solar ultraviolet radiation, which heats the stratosphere. It also absorbs infrared radiation emitted by the Earth's surface, effectively trapping heat in the troposphere. Therefore, the climate impact of changes in ozone concentrations varies with the altitude at which these ozone changes occur. The major ozone losses that have been observed in the lower stratosphere due to the human-produced chlorine- and bromine-containing gases have a cooling effect on the Earth's surface. On the other hand, the ozone increases that are estimated to have occurred in the troposphere because of surface-pollution gases have a warming effect on the Earth's surface, thereby contributing to the "greenhouse" effect.

In comparison to the effects of changes in other atmospheric gases, the effects of both of these ozone changes are difficult to calculate accurately. In the figure below, the upper ranges of possible effects for the ozone changes are indicated by the open bars, and the lower ranges are indicated by the solid bars.

As shown in the figure, increases in carbon dioxide is the major contributor to climate change. Carbon dioxide concentrations are increasing in the atmosphere primarily as the result of the burning of coal, oil, and natural gas for energy and transportation. The atmospheric abundance of carbon dioxide is currently about 30% above what it was 150 years ago. The relative impacts on climate of various other "greenhouse" gases are also shown on the figure.

There is an additional factor that indirectly links ozone depletion to climate change; namely, many of the same gases that are causing ozone depletion are also contributing to climate change. These gases, such as the chlorofluorocarbons (CFCs), are green-house gases, absorbing some of the infrared radiation emitted by the Earth's surface, thereby effectively heating the Earth's surface.

Conversely, changes in the climate of the Earth could affect the behavior of the ozone layer, because ozone is influenced by changes in the meteorological conditions and by changes in the atmospheric composition that could result from climate change. The major issue is that the stratosphere will most probably cool in response to climate change, therefore preserving over a longer time period the conditions that promote chlorine-caused ozone depletion in the lower stratosphere, particularly in polar regions. At present, the amplitude and extent of such a cooling, and therefore the delay in the recovery of the ozone layer, still have to be assessed.

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How severe is the ozone depletion now?
Stratospheric ozone depletion, caused by increasing concentrations of human-produced chemicals, has increased since the 1980s. The springtime loss in Antarctica is the largest depletion. Currently, in non-polar regions, the ozone layer has been depleted up to several percent compared with that of two decades ago.

As the figure below indicates, the magnitude of ozone depletion varies between the regions of the Earth. For example, there has been little or no ozone depletion in the tropics (about 20 degrees north and south of the equator). The magnitude of the depletion also depends on the season. From 1979 to 1997, the observed losses in the amount of ozone overhead have totaled about 5-6% for northern midlatitudes in winter and spring, about 3% for northern midlatitudes in summer and fall, and about 5% year round for southern midlatitudes. Since the early 1980s, the ozone hole has formed over Antarctica during every Southern Hemisphere spring (September to November), in which up to 60% of the total ozone is depleted. Since the early 1990s, ozone depletion has also been observed over the Arctic, with the ozone loss from January through late March typically being typically 20-25% in most of the recent years. All of these decreases are larger than known long-term natural variations.

The large increase in atmospheric concentrations of human-made chlorine and bromine compounds is responsible for the formation of the Antarctic ozone hole. Furthermore, the overwhelming weight of evidence indicates that it also plays a major role in the ozone depletion in the Arctic and at midlatitudes.

In addition to these long-term changes, transient effects have also been observed in the stratospheric ozone layer following major volcanic eruptions such as Mt. Pinatubo in 1991. During 1992 and 1993, ozone in many locations dropped to record low values. For example, springtime depletions exceeded 20% in some populated northern midlatitude regions, and the levels in the Antarctic ozone hole fell to the lowest values ever recorded. These unusually large, but short-term, ozone decreases of 1992 and 1993 are believed to be related in part to the large amounts of volcanic particles injected into stratosphere, which temporarily increased the ozone depletion caused by human-produced chlorine and bromine compounds, much as polar stratospheric clouds increase these chemicals' effect on ozone depletion in polar regions. Because these particles settle out of the stratosphere within a few years, the ozone concentrations have largely returned to the depleted levels consistent with the downward trend observed before the Mt. Pinatubo eruption. Should a similar eruption occur in the coming decade, ozone losses of the same magnitude might be expected, because the chlorine levels in the stratosphere will still be high.

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Is the ozone layer expected to recover?
The ozone depletion caused by human-produced chlorine and bromine compounds is expected to gradually disappear by about the middle of the 21st century as these compounds are slowly removed from the stratosphere by natural processes. This environmental achievement is due to the landmark international agreement to control the production and use of ozone-depleting substances. Full compliance would be required to achieve this expected recovery.

In 1987, the recognition of the potential for chlorine and bromine to destroy stratospheric ozone led to the Montreal Protocol on Substances that Deplete the Ozone Layer, as part of the 1985 Vienna Convention for the Protection of the Ozone Layer, to reduce the global production of ozone-depleting substances. Subsequently, global observations of significant ozone depletion have prompted Amendment to strengthen the treaty. The 1990 London Amendment calls for a ban on the production of the most damaging ozone-depleting substances by 2000 in developed countries and 2010 in developing countries. The 1992 Copenhagen Amendment changed the date of the ban to 1996 in developed countries. Further restrictions on ozone-depleting substances have been agreed upon in Vienna (1995) and Montreal (1997).

The figure below shows past and projected stratospheric abundances of chlorine and bromine without the Protocol, under the Protocol's original provisions, and under its subsequent agreements. Without the Montreal Protocol and its Amendment, continuing use of chlorofluorocarbons (CFCs) and other ozone-depleting substances would have increased the stratospheric abundances of chlorine and bromine tenfold by the mid-2050s compared with the 1980 amounts. Such high chlorine and bromine abundances would have caused very large ozone losses, which would have been far larger than the depletion observed at present.

In contrast, under the current international agreements that are now reducing the human-caused emissions of ozone-depleting gases, the net tropospheric concentrations of chlorine- and bromine-containing compounds started to decrease in 1995. Because 3 to 6 years are required for the mixing from the troposphere to the stratosphere, the stratospheric abundances of chlorine are starting to reach a constant level and will slowly decline thereafter. With full compliance, the international agreements will eventually eliminate most of the emissions of the major ozone-depleting gases. All other things being constant, the ozone layer would be expected to return to a normal state during the middle of the next century. This slow recovery, as compared with the relatively rapid onset of the ozone depletion due to CFC and bromine-containing halon emissions, is related primarily to the time required for natural processes to eliminate the CFCs and halons from the atmosphere. Most of the CFCs and halons have atmospheric residence times of about 50 to several hundred years.

However, the future state of the ozone layer depends on more factors than just the stratospheric concentrations of human-produced chlorine and bromine. It will also be affected to some extent by the changing atmospheric abundances of several other human-influenced constituents, such as methane, nitrous oxide, and sulfate particles, as well as by the changing climate of the Earth. As a result, the ozone layer is unlikely to be identical to the ozone layer that existed prior to the 1980s. Nevertheless, the discovery and characterization of the issue of ozone depletion from chlorine and bromine compound and a full global compliance with the international regulations on their emissions will have eliminated what would have been, as the figure illustrates, a major deterioration of the Earth's protective ultraviolet shield.

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Does depletion of the ozone layer increase ground-level ultraviolet radiation?
Yes, ultraviolet radiation at Earth’s surface increases as the amount of overhead total ozone decreases, because ozone absorbs ultraviolet radiation from the Sun. Measurements by ground-based instruments and estimates made using satellite data have confirmed that surface ultraviolet radiation has increased in regions where ozone depletion is observed.

Is depletion of the ozone layer the principal cause of climate change?
No, ozone depletion itself is not the principal cause of climate change. However, because ozone is a greenhouse gas, ozone changes and climate change are linked in important ways. Stratospheric ozone depletion and increases in global tropospheric ozone that have occurred in recent decades both contribute to climate change. These contributions to climate change are significant but small compared with the total contribution from all other greenhouse gases. Ozone and climate change are indirectly linked because ozone-depleting gases, such as the chlorofluorocarbons (CFCs), hydrochlorofluorocarbons (HCFCs), and halons, also contribute to climate change.

Is the depletion of the ozone layer leading to an increase in ground-level Ultraviolet radiation?
The depletion of the ozone layer leads, on the average, to an increase in ground-level ultraviolet radiation, because ozone is an effective absorber of ultra-violet radiation.

The Sun emits radiation over a wide range of energies, with about 2% in the form of high-energy, ultraviolet (UV) radiation. Some of this UV radiation (UV-B) is especially effective in causing damage to living beings, for example, sunburn, skin cancer, and eye damage to humans. The amount of solar UV radiation received at any particular location on the Earth's surface depends upon the position of the Sun above the horizon, the amount of ozone in the atmosphere, and local cloudiness and pollution. Scientists agree that, in the absence of changes in clouds or pollution, decreases in atmospheric ozone lead to increases in ground-level UV radiation.

The largest decreases in ozone during the past 15 years have been observed over Antarctica, especially during each September and October when the ozone hole forms. During the last several years, simultaneous measurements of UV radiation and total ozone have been made at several Antarctic stations. In the late spring, the biologically damaging ultraviolet radiation in parts of the Antarctic continent can exceed that in San Diego, California, where the Sun is much higher above the horizon.

In areas where smaller ozone depletion has been observed, UV-B increases are more difficult to detect. In particular, detection of trends in UV-B radiation associated with ozone decreases can be further complicated by changes in cloudiness, by local pollution, and by difficulties in keeping the detection instrument in precisely the same condition over many years. Prior to the late 1980s, instruments with the necessary accuracy and stability for measurement of small long-term trends in ground-level UV-B were not available. Therefore, the data from urban locations with older, less-specialized instruments provide much less reliable information, especially since simultaneous measurements of changes in cloudiness or local pollution are not available. When high-quality measurements have been made in other areas far from major cities and their associated air pollution, decreases in ozone have regularly been accompanied by increases in UV-B. This is shown in the figure below, where clear-sky measurements performed at six different stations demonstrate that ozone decreases lead to increased UV-B radiation at the surface in amounts that are in good agreement with that expected from calculations (the "model" curve).

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ECONOMIC CONSEQUENCES

Has the benefit of the Montreal Protocol been worth the cost?

Has the benefit of the Montreal Protocol been worth the cost?

Yes. Several attempts have been made to investigate the economic impacts of the problem of a depleted ozone layer. Such attempts meet with many problems. There are good reasons for concern for effects on humans, animals, plants and materials, but most of these cannot be estimated in quantitative terms. Calculating the economic impact of such effects is uncertain. Moreover, economic terms are applicable only to some of the effects, such as the cost of medical treatments, and the loss of production in fisheries and agriculture, and damage to materials; but what is the cost equivalent of suffering, of a person becoming blind or dying, or the loss of a rare plant or animal species?

In spite of all these difficulties, attempts have been made. The most comprehensive example is a study initiated by Environment Canada for the 10th anniversary of the Montreal Protocol on Substances that Deplete the Ozone Layer. In this study, 'Global Costs and Benefits of the Montreal Protocol' (1997), the costs were calculated for all measures taken internationally to protect the ozone layer, such as replacement of technologies using ozone-depleting substances. The benefits are the total value of the damaging effects avoided in this way. The total costs of the measures taken to protect the ozone layer were calculated to be 235 billion US (1997) dollars. The effects avoided world-wide, though far less quantifiable, were estimated to be almost twice that amount. This latter estimate included only reduced damage to fisheries, agriculture and materials. The cataracts and skin cancers, as well as the potential associated fatalities avoided, were listed as additional benefits, and not expressed in economic terms.

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STRATOSPHERIC OZONE IN THE FUTURE

How will recovery of the ozone layer be detected?
When is the ozone layer expected to recover?

How will recovery of the ozone layer be detected?
Scientists expect to detect the recovery of the ozone layer with careful comparisons of the latest ozone measurements with past values. Changes in total overhead ozone at various locations and in the extent and severity of the Antarctic “ozone hole” will be important factors in gauging ozone recovery. Natural variations in ozone amounts will limit how soon recovery can be detected with future ozone measurements.

When is the ozone layer expected to recover?
The ozone layer is expected to recover by the middle of the 21st century, assuming global compliance with the Montreal Protocol. Chlorine- and bromine-containing gases that cause ozone depletion will decrease in the coming decades under the provisions of the Protocol. However, volcanic eruptions in the next decades could delay ozone recovery by several years and the influence of climate change could accelerate or delay ozone recovery.

HEALTH EFFECTS

How do we balance the good and bad effects of sunlight on human health?
How strong is the evidence that UV-B radiation causes skin cancer in humans?
Should one have all moles removed to decrease the risk of skin cancer?
Do sunglasses protect against cataracts?

How do we balance the good and bad effects of sunlight on human health?
In general, moderate exposure to sunlight in the course of everyday life is not detrimental. This basic exposure evidently allows us to function normally, and it proves to be sufficient to maintain an adequate level of vitamin D (in combination with our dietary intake). While sunlight is important for physical health it also causes various adverse health effects such as skin cancer, ageing of the skin, eye disorders and suppression of the immune system. It is clear that excessive UV exposure should be avoided to minimise the risk of development of such disorders.

How strong is the evidence that UV-B radiation causes skin cancer in humans?
The evidence is strong. The earliest experimental evidence that UV-B radiation causes skin cancer was acquired with animals; in humans there was a clear association between sun exposure and skin cancer, but that did not point specifically to UV-B. In recent years the advancement of molecular biology has provided us with analyses that produce direct evidence that genetic alterations found in human skin carcinomas are indeed caused by UV-B radiation.

Should one have all moles removed to decrease the risk of skin cancer?
No, there is no evidence to suggest that removing all of the moles would reduce the risk of skin cancer. However, it is important to be alert to atypical moles, especially those exhibiting changes in appearance (in colour or at the edges), and to screen those individuals that are known to run a high risk, either from a family history of melanoma mortality or of atypical moles.

Do sunglasses protect against cataracts?
Sunglasses that markedly reduce the UV-exposure of the eyes will reduce UV damage, such as cataracts. The best protection is achieved by a combination of UV-absorbing glasses and a shielding against light coming into the eyes from the sides. However, some sunglasses may not effectively block UV radiation and eye damage may occur.

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DURATION OF EXPOSURE TO UV-B RADIATION

Is the UV amount one receives as a child important even in later years?

Is the UV amount one receives as a child important even in later years?
Yes. Children should not be overexposed to UV radiation: sunbathing should be strongly discouraged. UV exposure, and especially sunburns, in early life can substantially increase the skin cancer risk later in life (especially the risk of basal cell carcinoma and melanoma).

Even if the risk is related to total accumulated exposure, as appears to be the case for a part of the non-melanocytic skin cancers (SCC), exposures early in life still may carry a greater risk. There is a long lag time, typically of several decades, between exposure and the development of a tumour. Therefore, early exposures have a greater probability in resulting in a tumour.



IMPACT ON ANIMALS

Are hair-covered animals at any risk?
Will penguins be affected by the ozone hole?
Is UV-B radiation a factor in the decline of frogs and other amphibians?

Are hair-covered animals at any risk?
Yes. Skin cancer is found in almost all animals that have been studied in the long-term, for example, cattle, goats, sheep, cats, dogs, guinea pigs, rats, and mice. Direct effects of UV-B radiation on body parts which are covered by thick hair are negligible. However, even furred animals usually have exposed skin around mouth and nostrils, and sometimes on some other parts of the body. These parts, unless they are heavily pigmented, can be damaged by radiation.

Will penguins be affected by the ozone hole?
To our knowledge there are no studies concerning UV-B effects on penguins. As their eyes are exposed to a lot of UV due to the high reflectivity of snow and a marked enhancement during the ozone hole, investigation into the impact on penguins is desirable. The fact that penguins are visual predators, eating krill or fish in the water column, would make any eye damage an important issue for survival.

Is UV-B radiation a factor in the decline of frogs and other amphibians?
Possibly. Amphibian populations are in serious decline in many areas of the world, and scientists are seeking explanations for this. Most amphibian population declines are probably due to habitat destruction or habitat alteration. Some declines are probably the result of natural population fluctuations. Other explanations for the population declines, as well as the reductions in range of habitation, include disease, pollution, atmospheric changes and introduced competitors and predators. UV-B radiation is one agent that may act in conjunction with other stresses to adversely affect amphibian populations. Field studies in which embryos of frogs, toads, and salamanders were exposed to natural sunlight or to sunlight with UV-B radiation removed have shown conflicting results. Some studies resulted in increased embryonic mortality after UV-B exposure, whereas others show that current levels of UV-B radiation are not detrimental. Factors such as water depth, water colour, and the dissolved organic content of the water at the sites of egg deposition effectively reduce UV-B penetration through the water and reduce exposure to UV-B radiation at all life history stages. Biotic factors, such as jelly capsules around eggs, melanin pigmentation of eggs, and colour of larvae and metamorphosed forms, further reduce the effects of UV-B exposure.

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IMPACT ON AQUATIC LIFE

Does water effectively shield aquatic organisms from UV exposure?

Does water effectively shield aquatic organisms from UV exposure?
No. Pure water is quite transparent to UV radiation; a beam of UV-B radiation must travel over one-half kilometre through pure water in order to be completely absorbed. Natural waters do contain UV-absorbing substances, such as dissolved organic matter, that partly shields aquatic organisms from UV-B, but the degree of shielding varies widely from one water body to another. In clear ocean and lake waters ecologically-significant levels of UV-B can penetrate to several tens of meters; in contrast, in turbid rivers and wetlands UV-B may be completely absorbed within the top few decimetres. Most organisms in aquatic ecosystems, such as phytoplankton, live in the illuminated euphotic zone close to the water surface where exposure to UV-B can occur. In particular, UV-B radiation may damage those organisms that live at the surface of the water during their early life stages.


IMPACT ON TERRESTRIAL PLANT LIFE

What will be the effects of an increased UV-B radiation on crop and forest yields?
Can plants protect themselves against increased UV-B?

What will be the effects of an increased UV-B radiation on crop and forest yields?
There are some UV-B-sensitive varieties of crops that experience reductions in yield. However, there are also UV-B-tolerant varieties, providing the opportunity to breed and genetically engineer UV-B tolerant varieties. For commercial forests, tree breeding and genetic engineering may be used to improve UV-B tolerance. For unmanaged or natural forests, these methods are not an option. While many forest tree species appear to be UV-B tolerant, there is some evidence that UV-B effects, sometimes detrimental, can slowly accumulate from year to year. If this finding is a general phenomenon, this would be cause for concern since it would greatly complicate breeding efforts in commercial forests and negatively affect natural forests.

Can plants protect themselves against increased UV-B?
Yes, partly. Plants already have reasonable UV shielding; for most plants only a small proportion of the UV-B radiation striking a leaf actually penetrates very far into the inner tissues. Also, when exposed to an enhanced UV-B level, many species of plants can increase the UV-absorbing pigments in their tissues. Other adaptations include increased thickness of leaves which reduces the proportion of inner tissues exposed to UV-B radiation. Several repair mechanisms also exist in plants, as is the case for other organisms. This includes repair systems for DNA damage or oxidant injury. The net damage a plant experiences is the result of the balance among damage, protection and repair processes. For many plants, the net damage is negligible.

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GEOGRAPHIC CONSIDERATIONS

Is the increase in UV-B radiation caused by ozone depletion equivalent to that incurred by moving
Can organisms adjust to a changed UV environment?
Does ozone depletion pose any danger in the tropics?
Do we need to worry about relatively small increases in UV-B due to ozone depletion, when natural variability is so much larger?
Does one get higher UV exposures at higher elevations?
Does air pollution protect one from UV-B radiation?
Can changes in cloudiness cause larger UV changes than ozone depletion?
Are the risks of ultraviolet (UV) exposure at the beach less on a cloudy day?

Is the increase in UV-B radiation caused by ozone depletion equivalent to that incurred by moving several hundred kilometres towards the equator?
Yes, but this comparison does not nullify the serious impact of an ozone depletion, as is sometimes suggested by questions like this. The suggestion is based on a fallacy, namely, comparing a personal risk perception with the effect on a population. An elevation of say 10% in risk would not be noticeable for the person involved. For a population it is quite different. With regard to skin cancer such an increase could mean 100-200 extra cases a year per million people. This would be an important public health effect. However, movements of entire populations, or even ecosystems, do not usually occur in a human lifetime, and the comparison is therefore inappropriate.

Can organisms adjust to a changed UV environment?
Yes, many organisms can respond physiologically with changes such as development of UV screening compounds and additional layers of protective tissues. However, there are genetic limitations to the degree to which these physiological adjustments can take place for each organism. Some can adjust more effectively than others. Over long periods of time and several generations of populations, there is the possibility that genetic adaptation can develop as well. However, in organisms with moderately long life spans and small population sizes, the genetic adaptation is likely to be very slow.

Does ozone depletion pose any danger in the tropics?
Probably not. Increases in UV-B radiation are unlikely, since no significant trend in stratospheric ozone has been observed in the tropics. However, viewing the biosphere as a unit, there may be indirect effects of ozone depletion at other latitudes on tropical ecosystems. If ozone were to be depleted in the tropics, this would constitute a serious danger because of the naturally occurring high levels of UV-B radiation due to the high solar angles and already relatively low normal stratospheric ozone levels.

Do we need to worry about relatively small increases in UV-B due to ozone depletion, when natural variability is so much larger?
Yes. The change in UV-B from ozone depletion is systematically upward. The natural variability (e.g., from time of day, or clouds) can be larger, but goes in both directions, up and down. While the evidence for ozone depletion is very strong, there is little evidence for long-term changes in cloud cover.

Many detrimental effects of UV-B are proportional to the cumulative UV-B exposure. For example, skin cancer results from the total exposure accumulated over many years under both sunny and cloudy conditions. Any systematic increase in UV-B radiation will increase incidence among a population (as well as individual risk) regardless of the natural variability of the UV-B radiation.

Does one get higher UV exposures at higher elevations?
Yes. Higher elevations have less atmosphere overhead, as evidenced by the thinner air and lower atmospheric pressure. The increase in sun-burning UV radiation is typically about 5-10% for each kilometre of elevation, the exact number depending on the specific wavelength, solar angle, reflections, and other local conditions. Frequently, other factors besides thickness of the atmosphere cause even larger differences in UV radiation between elevations. Snow is more common at higher elevations, and reflections from it can lead to very large increases in exposure.
Lower locations tend to have more haze and more polluted atmosphere which can block some UV radiation.

Does air pollution protect one from UV-B radiation?
Yes, but at a high price. Air pollution is generally undesirable due to the numerous other serious problems associated with it, including respiratory illness, eye irritation, and damage to vegetation. While most of the atmospheric ozone resides in the stratosphere, some ozone is also made in the troposphere by the chemical interactions of pollutants such as nitrogen oxides and hydrocarbons. This tropospheric ozone is a component of the photochemical smog found in many polluted areas. Airborne particles (smoke, dust, sulphate aerosols) can also block UV radiation, but they can also increase the amount of scattered light (haze) and therefore increase the UV exposure of side-facing surfaces (e.g., face, eyes).

No single value can be given for the amount of UV-B reduction by pollution, because pollution events tend to be highly variable and local. Comparisons of measurements made in industrialised regions of the Northern Hemisphere (e.g., central Europe) and in very clean locations at similar latitudes in the Southern Hemisphere (e.g., New Zealand) suggest pollution-related UV-B reductions can be important.

Can changes in cloudiness cause larger UV changes than ozone depletion?
Long-term trends in cloud type and amount are largely unknown due to the relatively short data record of comprehensive cloud observations, and the high variability of clouds on inter-annual and longer time scales. Some evidence exists showing that, at least over the time span of satellite-based ozone measurements, changes in cloud cover have been much less important than stratospheric ozone reductions in causing surface UV changes.

Are the risks of ultraviolet (UV) exposure at the beach less on a cloudy day?
Not necessarily. The effect of clouds on UV radiation is as varied as the clouds themselves. Fully overcast skies lead to reductions in surface UV irradiance. On average, scattered or broken clouds also cause reductions, but short-term or localised UV levels can be larger than for cloud-free skies if direct sunlight is also present. Clouds tend to randomise the directions of the incoming radiation (because of scattering) so that a hat may provide less protection on a cloudy day relative to a clear day.

Furthermore, people often change their behaviour on cloudy days. If they spend more time out in the open, or forego the use of sunscreen, they may end up with a very bad sunburn. In general, less UV radiation is received per hour under an overcast sky than under a clear sky, but extending one's stay at the beach may easily compensate for this effect. A completely cloud-covered sky may still transmit substantial amounts of UV-B radiation. In principle, any amount of UV-B radiation exposure contributes to the skin cancer risk.


SUNBATHING

Will sunscreens protect one from harmful effects of increased UV-B radiation?
Will getting a suntan help prevent skin cancer?
Is tanning with UV lamps safer than with sunlight?

Will sunscreens protect one from harmful effects of increased UV-B radiation?
Not always. Sunscreens applied to human skin limit the penetration of UV radiation into the skin, and thus sunburn can be prevented. Sunscreens were primarily developed for this purpose. The effectiveness of sunscreens in protecting against skin cancer and immune suppressions is under debate. Any effectiveness in these respects may well be lost if the sunscreen is used to stay out in the sunlight longer than would be done without the sunscreen. It should also be kept in mind that there are other ways to protect the skin. These include staying out of the sunlight during the hours when the UV-B is maximal around solar noon, seeking the shade, wearing clothes, and especially hats.

Will getting a suntan help prevent skin cancer?
No. There is no evidence that getting a suntan will help prevent skin cancer. The UV exposure needed to acquire the tan adds to the skin cancer risk. The fact that one is able to tan well does, however, signify that the personal risk is lower (by a factor of 2 to 3) than for people who do not tan. Naturally dark-skinned people have a built-in protection of their skin against sunlight.

Is tanning with UV lamps safer than with sunlight?
No. The risks are approximately equal. For some time it was hoped that UV lamps could be made safer by making more use of long-wavelength (UV-A) radiation. That type of radiation is much less carcinogenic than the shorter-wavelength UV-B radiation, but one needs more UV-A than UV-B for acquiring a tan.

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